This search combines search strings from the content search (i.e. "Full Text", "Author", "Title", "Abstract", or "Keywords") with "Article Type" and "Publication Date Range" using the AND operator.
Beilstein J. Org. Chem. 2015, 11, 1340–1351, doi:10.3762/bjoc.11.144
Graphical Abstract
Scheme 1: Reaction of carbon dioxide with epoxide to yield alternating polycarbonates, polyethercarbonates or...
Scheme 2: Epoxide and CO2 copolymerisation by homogeneous Cr(III)– and Al(III)–salen complexes.
Figure 1: The tri-coordinated di-iminate zinc–alkoxide complex [(BDI)ZnOCH3].
Scheme 3: Heterogeneous zinc dicarboxylates for the copolymerisation of CO2 and epoxides. (* = End group of p...
Scheme 4: Backbiting mechanism for the formation of cyclic carbonates.
Scheme 5: Two-step pathway for the cycloaddition of propylene oxide and CO2 in the ionic liquid 1-butyl-3-met...
Scheme 6: Formation of copper(I) cyanoacetate for the activation of CO2.
Scheme 7: Activation of CO2 by nucleophilic attack of bromide in the Re(I)-catalysed cycloaddition.
Scheme 8: Direct catalytic carboxylation of aliphatic compounds and arenes by rhodium(I)– and ruthenium(II)–p...
Scheme 9: Insertion of carbon dioxide into a metal–oxygen bond via a cyclic four-membered transition state. R...
Scheme 10: Facile CO2 uptake by zinc(II)–tetraazacycloalkanes.
Figure 2: The [(2-hydroxyethoxy)CoIII(salen)(L)] complex chosen as catalyst model for the calculations; 1: R1...
Figure 3: The two most relevant configurations of [(2-hydroxyethoxy)CoIII(salen)(L)] complexes. The left-hand...
Figure 4: Carbon dioxide insertion into the cobalt(III)–alkoxide bond of [(2-hydroxyethoxy)CoIII(salen)(L)] c...
Figure 5: Energy relationship between the activation barrier and the reaction energy of the CO2 incorporation...
Beilstein J. Org. Chem. 2015, 11, 675–677, doi:10.3762/bjoc.11.76
Figure 1: The carbon dioxide molecule.
Figure 2: Examples of highly reactive molecules that are isoelectronic to carbon dioxide.
Figure 3: Threefold reactivity of carbon dioxide and examples for different activation modes for CO2 involvin...
Beilstein J. Org. Chem. 2015, 11, 42–49, doi:10.3762/bjoc.11.7
Scheme 1: Structural motif of two important types of catalysts and typical substrate specificity in the copol...
Scheme 2: Binuclear Zn(II) complexes [LZn2](CF3SO3)2 (1, KOP113) and [LZn2](p-TSO3)2 (2, KOP115) explored in ...
Scheme 3: Copolymerisation of CO2 and cyclohexene oxide (*: end groups of the polymer chain).
Figure 1: Time-resolved IR spectra of the copolymerisation of CO2 and CHO with catalyst 1 showing the formati...
Figure 2: Time–concentration profile of the copolymerisation of CO2 and CHO in the presence of catalytic amou...
Figure 3: Carbonate region of the time-resolved IR spectra recorded during the copolymerisation of CO2 and cy...
Figure 4: Time–concentration profile of the copolymerisation of CO2 and CHO in the presence of catalytic amou...
Scheme 4: Proposed inner-sphere mechanism for the copolymerisation of CO2 and CHO with binuclear zinc complex...